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Kusky, Timothy M.; Traore, Alhousseyni
doi: 10.1029/2022gc010797pmid: N/A
In a new study, Wu, Wang, Zhou, Zhao, Haproff, et al. (2022, https://doi.org/10.1029/2022GC010662) present a comprehensive study of the North Margin Orogen of the North China Craton (NCC), showing that older accreted rocks in this belt preserve a record of active margin magmatism from 2.2 to 2.0 Ga, followed by collisional tectonics, marked by mélange and mylonitic shear zones, then granulite facies metamorphism at 1.9–1.8 Ga, marking the final collision of the NCC with the Columbia Supercontinent. The multidisciplinary studies presented in this work support earlier suggestions that the North China Craton amalgamated during accretionary orogenesis in the Neoarchean to earlier Paleoproterozoic, and that the late widespread 1.85 Ga high‐grade metamorphism is craton‐wide in scale, and not confined to a narrow orogen in the center of the craton. This new understanding creates new possibilities for refining reconstructions of one of Earth's earliest, best documented supercontinents, showing a globally linked plate network at 1.85 Ga, and suggests drastic new correlations and models for mineral resource exploration.
Park, Jinsub; Jung, Jaewoo; Ko, Youngtak; Lee, Yongmoon; Yang, Kiho
doi: 10.1029/2022gc010768pmid: N/A
Variations in the geochemistry and mineralogical compositions of ferromanganese (Fe‐Mn) nodules are closely related to variations in environmental parameters. Therefore, analysis of Fe‐Mn nodules can reconstruct the paleo‐ocean environment. Here, three differently shaped Fe‐Mn nodules were collected from the open seamount 9‐1 of the western Pacific Magellan Seamount. Geochemical and mineralogical analyses were conducted using micro X‐ray fluorescence (μ‐XRF) and Synchrotron X‐ray powder diffraction to reconstruct the paleo‐ocean environment. We found that the shape of the three nodules was different; however, the variations in their geochemical and mineralogical properties were similar. For all three nodules, the μ‐XRF elemental distribution revealed a distinct alternation between the Mn‐rich and Fe‐rich layers. The Mn‐rich and Fe‐rich layers surrounded the nuclei and appeared as concentric circles. Fe‐rich and Mn‐rich layers exhibited low Mn/Fe ratios (<2.5) and were dominated by vernadite, whereas layers with high Mn/Fe ratios (>2.5) were dominated by todorokite, respectively. These findings suggest an early diagenesis process at tabletop of the Magellan Seamount. The high contents of Ca and P and the existence of carbonate fluorapatite in the center of Fe‐Mn nodules indicate that the formation of these nodules began during the Miocene phosphatization event (19–16 Ma). In the early stages of nodule formation, a diagenetic process drove Fe‐Mn nodule formation. Because of global cooling from 9 Ma, early diagenesis was weakened, after which the formation of hydrogenetic Fe‐Mn nodules became dominant. As a result, variations in oxygen minimum zones and oxic‐suboxic fronts were recorded in Fe‐Mn nodules from tabletop of the seamount.
Gans, P. B.; Mortimer, N.; Patriat, M.; Turnbull, R. E.; Crundwell, M. P.; Agranier, A.; Calvert, A. T.; Seward, G.; Etienne, S.; Durance, P. M. J.; Campbell, H. J.; Collot, J.
doi: 10.1029/2022gc010670pmid: N/A
The 2015 VESPA voyage (Volcanic Evolution of South Pacific Arcs) was a seismic and rock dredging expedition to the Loyalty and Three Kings Ridges and South Fiji Basin. In this paper we present 33 40Ar/39Ar, 22 micropaleontological, and two U/Pb ages for igneous and sedimentary rocks from 33 dredge sites in this little‐studied part of the southwest Pacific Ocean. Igneous rocks include basalts, dolerites, basaltic andesites, trachyandesites, and a granite. Successful Ar/Ar dating of altered and/or low‐K basalts was achieved through careful sample selection and processing, detailed petrographic and element mapping of groundmass, and incremental heating experiments on both phenocryst and groundmass separates to interpret the complex spectra produced by samples having multiple K reservoirs. The 40Ar/39Ar ages of most of the sampled lavas, irrespective of composition, are latest Oligocene to earliest Miocene (25–22 Ma); two are Eocene (39–36 Ma). The granite has a U/Pb zircon age of 23.6 ± 0.3 Ma. 40Ar/39Ar lava ages are corroborated by microfossil ages from associated sedimentary rocks. The VESPA lavas are part of a >3,000 km long disrupted belt of Eocene to Miocene subduction‐related volcanic rocks. The belt includes arc rocks in Northland New Zealand, Northland Plateau, Three Kings Ridge, and Loyalty Ridge and, speculatively, D’Entrecasteaux Ridge. This belt is the product of superimposed Eocene and Oligocene‐Miocene remnant volcanic arcs that were stranded along and near the edge of Zealandia while still‐active arc belts migrated east with the Pacific trench.
Archer, Gregory J.; Budde, Gerrit; Worsham, Emily A.; Stracke, Andreas; Jackson, Matthew G.; Kleine, Thorsten
doi: 10.1029/2022gc010688pmid: N/A
Ocean island basalts (OIB) show variable 182W deficits that have been attributed to either early differentiation of the mantle or core‐mantle interaction. However, 182W variations may also reflect nucleosynthetic isotope heterogeneity inherited from Earth's building material, which would be evident from correlated 182W and 183W anomalies. Some datasets for OIB indeed show hints for such correlated variations, meaning that a nucleosynthetic origin of W isotope anomalies in OIB cannot be excluded. We report high‐precision W isotope data for OIB from Samoa and Hawaii, which confirm previously reported 182W deficits for these samples, but also demonstrate that none of these samples have resolvable 183W anomalies. These data therefore rule out a nucleosynthetic origin of the 182W deficits in OIB, which most likely reflect the entrainment of either core material or an overabundance of late‐accreted materials within OIB mantle sources. If these processes occurred over Earth's history, they may have also been responsible for shifting the 182W composition of the bulk mantle to its modern‐day value. We also report Mo isotope data for some Hawaiian OIB, which reveal no resolved nucleosynthetic Mo isotopic anomalies. This is consistent with inheritance of 182W deficits in OIB from the addition of either core or late‐accreted material, but only if these materials have a non‐carbonaceous (NC) meteorite‐like heritage. As such, these data rule out significant contributions of carbonaceous chondrite (CC)‐like materials to either Earth's core or late accretion.
Roxerová, Zuzana; Machek, Matěj; Kusbach, Vladimír K.; Vávrová, Anna
doi: 10.1029/2022gc010630pmid: N/A
The majority of the strain in Earth crust and upper mantle is localized to the high strain zones developed at ductile‐to‐brittle condition at kilometer‐to‐micrometer scale. Therefore, they represent the key to understanding the deformation evolution of the lithosphere. The finite strain pattern recorded within these zones has been therefore a subject of research in geology. The methods studying rock magnetism such as the anisotropy of magnetic susceptibility (AMS) are frequently used techniques to characterize and quantify deformation and flow record in rocks. Numerous sedimentary, subsolidus and submagmatic deformation zones exhibit typical evolution of the AMS ellipsoid across the strain gradient suggesting indirect not straightforward correlation between AMS and strain ellipsoids. To document spatiotemporal and internal fabric evolution during strain localization, pure shear, simple shear, and shear zone (SZ) analog experiments were performed using shear‐thinning thixotropic material of plaster of Paris. The experimental results closely resemble the record from natural SZs in sedimentary rock systems but also in subsolidus SZs and submagmatic mushy systems. The magnetic fabric evolution across deformation zones is interpreted to be associated with the intersection and transposition of preexisting primary fabric with shear fabrics and evolution of synkinematic subfabrics. Their development is attributed to localization of deformation at microscale due to the self‐organized slip of anisometric particles forming microshear planes reflecting the symmetry of deformation. The experimental results when confronted with the natural examples implies that the localization and partitioning of deformation is one of the most important factors for the interpretation of AMS in deformation zones.
Hoyer, P. A.; Haase, K. M.; Regelous, M.; Fluteau, F.
doi: 10.1029/2022gc010750pmid: N/A
Large Igneous Provinces (LIPs) are unusual volcanic events in which massive amounts of melt (∼106 km3) erupt in relatively short time periods (<106 years). Most LIP magmas have undergone extensive fractional crystallization and crustal contamination, but the crustal magmatic plumbing systems and the processes triggering eruptions are poorly understood. We present new major and trace element and radiogenic isotope data for 43 individual lava flows from a continuous 1,200 m thick stratigraphic profile through the upper, most voluminous part of the Deccan LIP (Bushe to Mahabaleshwar Formations). Eruption rates for this section are constrained by published paleomagnetic directions and absolute U‐Pb ages for zircons from weathered flow tops exposed in the profile. We find four magmatic sequences each lasting ∼104–∼105 years during which major and trace element compositions change systematically, followed by an abrupt change in geochemistry at the start of a new sequence. Within each sequence, the MgO content and proportion of crustal contamination decrease progressively, indicating a continuous replenishment of the associated magma reservoirs with less contaminated but more evolved melts. These geochemical signatures are best explained by repeated episodes of melt recharge, mixing, and eruption of variably evolved magmas originating from relatively small magma reservoir located in different crustal levels.
Hua, J.; Fischer, K. M.; Gazel, E.; Parmentier, E. M.; Hirth, G.
doi: 10.1029/2022gc010605pmid: N/A
The origin of widespread volcanism far from plate boundaries and mantle plumes remains a fundamental unsolved question. An example of this puzzle is the Anatolian region, where abundant intraplate volcanism has occurred since 10 Ma, but a nearby underlying plume structure in the deep mantle is lacking. We employed a combination of seismic and geochemical data to link intraplate volcanism in Anatolia to a trail of magmatic centers leading back to East Africa and its mantle plume, consistent with northward asthenospheric transport over a ∼2,500 km distance. Joint modeling of seismic imaging and petrological data indicates that the east Anatolian mantle potential temperature is higher than the ambient mantle (∼1,420°C). Based on multiple seismic tomography models, the Anatolian upper mantle is likely connected to East Africa by an asthenospheric channel with low seismic velocities. Along the channel, isotopic signatures among volcanoes are consistent with a common mantle source, and petrological data demonstrate similar elevated mantle temperatures, consistent with little cooling in the channel during the long‐distance transport. Horizontal asthenospheric pressure gradients originating from mantle plume upwelling beneath East Africa provide a mechanism for high lateral transport rates that match the relatively constant mantle potential temperatures along the channel. Rapid long‐distance asthenospheric flow helps explain the widespread occurrence of global intraplate magmatism in regions far from deeply‐rooted mantle plumes throughout Earth history.
Jones, Cole R.; Capuano, Regina M.
doi: 10.1029/2022gc010601pmid: N/A
Cation mole precents (XCa, XMg, and XNa) on clay minerals in a siliciclastic coastal aquifer calculated from groundwater compositions, can aid in distinguishing fluvial from marine sediments and locate the fluvial/marine transition zone. The clay‐cation compositions of two clay‐rich siliciclastic coastal aquifers calculated from the composition of the groundwater were compared to the location of fluvial, fluvial‐marine transition and marine environments identified by traditional core, well log and paleontological analyses. The traditionally defined fluvial depositional environment is distinguished by clays with low XNa < 8% (for 92% of the samples) and high XCa from 55% to 98% with the remainder XMg. In comparison, the traditionally defined marine depositional environment is distinguished by clays with higher XNa > 8.0% (for 86% of the samples) and lower XCa ranging from 5% to 39% with the remainder XMg. The traditionally defined fluvial/marine transition zone has values overlapping the fluvial and marine end members, with 59% with XNa < 8% (fluvial) and 41% with XNa > 8% (marine), and XCa ranging from 45% to 98% with the remainder XMg. Calculations support that the excess Na (XNa > 8%) on marine clays can be retained for 10s of millions of years despite flushing with meteoric water, because of the high clay content in marine sediments. The calculated cation composition of clays deposited from river water are XNa < 8%. In contrast XNa 8%–54% is possible for seawater equilibrated clays supporting that the values found in the different depositional zones are possible. Calculated cation compositions might supplement traditional stratigraphic interpretations in distinguishing fluvial/marine depositional environments.
Lucarelli, Jamie K.; Carroll, Hannah M.; Ulrich, Robert N.; Elliott, Ben M.; Coplen, Tyler B.; Eagle, Robert A.; Tripati, Aradhna
doi: 10.1029/2022gc010458pmid: 37829604
Carbonate clumped isotope geochemistry has primarily focused on mass spectrometric determination of m/z 47 CO2 for geothermometry, but theoretical calculations and recent experiments indicate paired analysis of the m/z 47 (13C18O16O) and m/z 48 (12C18O18O) isotopologues (referred to as Δ47 and Δ48) can be used to study non‐equilibrium isotope fractionations and refine temperature estimates. We utilize 5,448 Δ47 and 3,400 Δ48 replicate measurements of carbonate samples and standards, and 183 Δ47 and 195 Δ48 replicate measurements of gas standards from 2015 to 2021 from a multi‐year and multi‐instrument data set to constrain Δ47 and Δ48 values for 27 samples and standards, including Devils Hole cave calcite, and study equilibrium Δ47‐Δ48, Δ47‐temperature, and Δ48‐temperature relationships. We compare results to previously published findings and calculate equilibrium regressions based on data from multiple laboratories. We report acid digestion fractionation factors, Δ*63‐47 and Δ*64‐48, and account for their dependence on the initial clumped isotope values of the mineral.
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