TY - JOUR
AU - Antoni, Gunnar
AB - Herein, we present a new rapid, efficient, and low‐cost radiosynthetic protocol for the conversion of 11CO2 to 11CO and its subsequent application in Pd‐mediated reactions of importance for PET applications. This room‐temperature methodology, using readily available chemical reagents, is carried out in simple glass vials, thus eliminating the need for expensive and specialized high‐temperature equipment to access 11CO. With this fast and near‐quantitative conversion of 11CO2 into 11CO, aryl and heteroaryl iodides were easily converted into a broad selection of biologically active amides in radiochemical yields ranging from 29–84 %.
TI - Rapid and Efficient Conversion of 11CO2 to 11CO through Silacarboxylic Acids: Applications in Pd‐Mediated Carbonylations
JF - Chemistry - A European Journal
DO - 10.1002/chem.201503262
DA - 2015-01-01
UR - https://www.deepdyve.com/lp/wiley/rapid-and-efficient-conversion-of-11co2-to-11co-through-silacarboxylic-W5QzOp70B8
SP - 17601
EP - 17604
VL - 21
IS - 49
DP - DeepDyve
ER -