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Stereospecific Sulfur‐Mediated Cleavage of a Spirocyclobutanone: Synthesis of a Fully Functional Precursor to the CP Compounds

Stereospecific Sulfur‐Mediated Cleavage of a Spirocyclobutanone: Synthesis of a Fully Functional... A reaction sequence made up of a Sakurai reaction, ketene cyclization, sulfur‐directed Baeyer–Villiger reaction, and tandem lactone cleavage/isomerization provided the fully functionalized core of the CP compounds. Key steps were the methanolysis of 1, which leads via 2 to the CP precursor 3. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Angewandte Chemie International Edition Wiley

Stereospecific Sulfur‐Mediated Cleavage of a Spirocyclobutanone: Synthesis of a Fully Functional Precursor to the CP Compounds

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Publisher
Wiley
Copyright
© 1999 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
ISSN
1433-7851
eISSN
1521-3773
DOI
10.1002/(SICI)1521-3773(19990517)38:10<1485::AID-ANIE1485>3.0.CO;2-1
Publisher site
See Article on Publisher Site

Abstract

A reaction sequence made up of a Sakurai reaction, ketene cyclization, sulfur‐directed Baeyer–Villiger reaction, and tandem lactone cleavage/isomerization provided the fully functionalized core of the CP compounds. Key steps were the methanolysis of 1, which leads via 2 to the CP precursor 3.

Journal

Angewandte Chemie International Edition – Wiley

Published: May 17, 1999

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