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References (23)
-
B. Sauer, M. Kawaguchi, Hyuk Yu (1987)
A surface light scattering study of poly(ethylene oxide) and poly(vinyl acetate) at the air-water and heptane/water interfacesMacromolecules, 20
-
R. Skarlupka, Y. Seo, Hyuk Yu (1997)
Electrocapillary Wave Studies of Oligomeric Ethers: Poly(dimethylsiloxane) and Poly(ethylene glycol)Macromolecules, 30
-
C. Gau, Hyuk Yu, G. Zografi (1994)
Surface Viscoelasticity of β-Casein Monolayers at the Air/Water Interface by Electrocapillary Wave DiffractionJournal of Colloid and Interface Science, 162
-
N. Jarvis (1966)
Surface Viscosity of Polydimethylsiloxane MonolayersThe Journal of Physical Chemistry, 70
-
S. Granick, S. Clarson, T. Formoy, J. Semlyen (1985)
Studies of cyclic and linear poly(dimethylsiloxanes): 18. Surface pressures of the monolayers in the plateau regionPolymer, 26
-
O. Girard, J. Cohen-Addad (1991)
Silica-siloxane mixtures : surface saturation process of particles. KineticsPolymer, 32
-
R. Skarlupka, Y. Seo, Hyuk Yu (1998)
A study of the surface viscoelasticity of poly(vinyl acetate) at the air-water interface using the electrocapillary wave diffraction techniquePolymer, 39
-
E. Helfand, Z. Wasserman (1978)
Block Copolymer Theory. 5. Spherical DomainsMacromolecules, 11
-
K. Shull, E. Kramer (1990)
Mean-field theory of polymer interfaces in the presence of block copolymersMacromolecules, 23
-
V. Vogel, D. Möbius (1989)
Resonance of transverse capillary and longitudinal waves as a tool for monolayer investigations at the air-water interface.Langmuir, 5
-
M. Coleman, J. Graf, P. Painter (1995)
Specific interactions and miscibility of polymer blends -
E. Lucassen-Reynders, J. Lucassen (1970)
Properties of capillary wavesAdvances in Colloid and Interface Science, 2
-
C. Fleischer, A. Morales, J. Koberstein (1994)
Interfacial Modification Through End Group Complexation in Polymer BlendsMacromolecules, 27
-
C. Gau, H. Yu, G. Zografi (1993)
Surface viscoelasticity of hydroxypropyl cellulose and hydroxyethyl cellulose monolayers at the air/water interfaceMacromolecules, 26
-
Kenichi Ito, B. Sauer, R. Skarlupka, M. Sano, Hyuk Yu (1990)
Dynamic interfacial properties of poly(ethylene oxide) and polystyrene at toluene/water interfaceLangmuir, 6
-
E. Mann, D. Langevin (1991)
Poly(dimethylsiloxane) molecular layers at the surface of water and of aqueous surfactant solutionsLangmuir, 7
-
E. Helfand, Z. Wasserman (1976)
Block Copolymer Theory. 4. Narrow Interphase ApproximationMacromolecules, 9
-
C. Stenvot, D. Langevin (1988)
Study of viscoelasticity of soluble monolayers using analysis of propagation of excited capillary wavesLangmuir, 4
-
D. Langevin (1990)
Optical studies of fluid interfaces -
S. Anastasiadis, I. Gancarz, J. Koberstein (1988)
Interfacial tension of immiscible polymer blends: temperature and molecular weight dependenceMacromolecules, 21
-
S. Granick (1985)
Surface pressure of linear and cyclic poly(dimethylsiloxane) in the transition regionMacromolecules, 18
-
A. Patel, T. Cosgrove, J. Semlyen, J. Webster, J. Scheutjens (1994)
Adsorption studies of different end-functionalised linear poly(dimethylsiloxane)Colloids and Surfaces A: Physicochemical and Engineering Aspects, 87
-
S. Hård, R. Neuman (1987)
Viscoelasticity of monomolecular films: A laser light-scattering studyJournal of Colloid and Interface Science, 120
- Publisher
- Wiley
- Copyright
- Copyright © 1998 Society of Plastics Engineers
- ISSN
- 0032-3888
- eISSN
- 1548-2634
- DOI
- 10.1002/pen.10239
- Publisher site
- See Article on Publisher Site
Abstract
The monolayer behavior of different end‐functionalized poly(dimethyl siloxane)s (PDMSs) and a block copolymer, poly(dimethyl siloxane‐co‐ethylene oxide) (PDMS‐co‐EO) spread on an oligomeric poly(ethylene glycol) (PEG) substrates, were studied by means of electrocapillary wave diffraction (ECWD). Over a relatively small temperature range (40–70°C), the damping constant was more dependent on temperature than on the wave vector. Different surface layer properties were observed for two PDMS: one terminated with a methyl group (PDMS‐CH3) and the one terminated with a hydroxy group (PDMS‐OH). PDMS‐OH showed a larger reduction in surface tension compared to PDMS‐CH3 because of a higher interfacial affinity with PEG, which indicated that its monolayer surface activity was weaker. A lower surface elasticity of PDMS‐OH than that of PDMS‐CH3 supported that conclusion. The block copolymer showed no surface activity, since the short siloxane moiety did not repel the strong interaction between PEG and the ethylene oxide.
Journal
Polymer Engineering & Science – Wiley
Published: May 1, 1998