Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/royal-society-of-chemistry/experimental-and-theoretical-evidence-that-electrostatics-governs-easy-4WvQOpcekA
References (25)
-
Peng Zhang, Yun-Nan Guo, Jinkui Tang (2013)
Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategiesCoordination Chemistry Reviews, 257
-
Goulven Cosquer, Fabrice Pointillart, Julie Jung, B. Guennic, S. Golhen, O. Cador, Y. Guyot, A. Brenier, O. Maury, L. Ouahab (2014)
Alkylation Effects in Lanthanide Complexes Involving Tetrathiafulvalene Chromophores: Experimental and Theoretical Correlation between Magnetism and Near‐Infrared EmissionEuropean Journal of Inorganic Chemistry, 2014
-
N. Chilton, S. Langley, B. Moubaraki, A. Soncini, S. Batten, K. Murray (2013)
Single molecule magnetism in a family of mononuclear β-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetryChemical Science, 4
-
D. Woodruff, R. Winpenny, R. Layfield (2013)
Lanthanide single-molecule magnets.Chemical reviews, 113 7
-
N. Jones (2011)
Materials science: The pull of stronger magnetsNature, 472
-
Jumei Tian, Bo Li, Xiaoying Zhang, Xiaolei Li, Xiaoliang Li, Jingping Zhang (2013)
Three novel 1D lanthanide-carboxylate polymeric complexes: syntheses, crystal structures and magnetic analyses.Dalton transactions, 42 23
-
Kévin Bernot, L. Bogani, A. Caneschi, D. Gatteschi, R. Sessoli (2006)
A family of rare-earth-based single chain magnets: playing with anisotropy.Journal of the American Chemical Society, 128 24
-
H. Miyasaka, M. Yamashita (2007)
A look at molecular nanosized magnets from the aspect of inter-molecular interactions.Dalton transactions, 4
-
J. Launay, M. Verdaguer (2013)
Electrons in Molecules: From Basic Principles to Molecular Electronics -
Peng Zhang, Li Zhang, Chao Wang, Shufang Xue, Shuang-Yan Lin, Jinkui Tang (2014)
Equatorially coordinated lanthanide single ion magnets.Journal of the American Chemical Society, 136 12
-
N. Chilton, D. Collison, E. McInnes, R. Winpenny, A. Soncini (2013)
An electrostatic model for the determination of magnetic anisotropy in dysprosium complexesNature Communications, 4
-
François Natur, Guillaume Calvez, C. Daiguebonne, O. Guillou, Kévin Bernot, J. Ledoux, L. Pollès, C. Roiland (2013)
Coordination polymers based on heterohexanuclear rare earth complexes: toward independent luminescence brightness and color tuning.Inorganic chemistry, 52 11
-
F. Habib, M. Murugesu (2013)
Lessons learned from dinuclear lanthanide nano-magnets.Chemical Society reviews, 42 8
-
F. Cinti, A. Rettori, M. Pini, M. Mariani, E. Micotti, A. Lascialfari, N. Papinutto, A. Amato, A. Caneschi, D. Gatteschi, M. Affronte (2010)
Experimental validation of Villain's conjecture about magnetic ordering in quasi-1D helimagnetsJournal of Magnetism and Magnetic Materials, 322
-
Kévin Bernot, J. Luzón, A. Caneschi, D. Gatteschi, R. Sessoli, L. Bogani, A. Vindigni, A. Rettori, M. Pini (2009)
Spin canting in a Dy-based single-chain magnet with dominant next-nearest-neighbor antiferromagnetic interactionsPhysical Review B, 79
-
R. Glauber (1963)
Time‐Dependent Statistics of the Ising ModelJournal of Mathematical Physics, 4
-
J. Luzón, R. Sessoli (2012)
Lanthanides in molecular magnetism: so fascinating, so challenging.Dalton transactions, 41 44
-
Robin Blagg, L. Ungur, F. Tuna, J. Speak, P. Comar, D. Collison, W. Wernsdorfer, E. McInnes, L. Chibotaru, R. Winpenny (2013)
Magnetic relaxation pathways in lanthanide single-molecule magnets.Nature chemistry, 5 8
-
(2013)
{Dy(α-fur)3}n: from double relaxation single-ion magnet behavior to 3D ordering.Dalton transactions, 42 28
-
L. Lecren, W. Wernsdorfer, Yang-guang Li, A. Vindigni, H. Miyasaka, R. Clérac (2007)
One-dimensional supramolecular organization of single-molecule magnets.Journal of the American Chemical Society, 129 16
-
Marie-Emmanuelle Boulon, G. Cucinotta, J. Luzón, Chiara Degl'Innocenti, M. Perfetti, Kévin Bernot, Guillaume Calvez, A. Caneschi, R. Sessoli (2013)
Magnetic anisotropy and spin-parity effect along the series of lanthanide complexes with DOTA.Angewandte Chemie, 52 1
-
Ying Wang, Xi-Li Li, Tianwei Wang, You Song, X. You (2010)
Slow relaxation processes and single-ion magnetic behaviors in dysprosium-containing complexes.Inorganic chemistry, 49 3
-
G. Novitchi, G. Pilet, L. Ungur, V. Moshchalkov, W. Wernsdorfer, L. Chibotaru, D. Luneau, A. Powell (2012)
Heterometallic CuII/DyIII 1D chiral polymers: chirogenesis and exchange coupling of toroidal moments in trinuclear Dy3 single molecule magnetsChemical Science, 3
-
Xiao-Yi Yi, Kévin Bernot, O. Cador, J. Luzón, Guillaume Calvez, C. Daiguebonne, O. Guillou (2013)
Influence of ferromagnetic connection of Ising-type Dy(III)-based single ion magnets on their magnetic slow relaxation.Dalton transactions, 42 19
-
K. Cole, R. Cole (1941)
Dispersion and Absorption in Dielectrics I. Alternating Current CharacteristicsJournal of Chemical Physics, 9
- Datasource
- Royal Society of Chemistry
- Publisher site
- See Article on Publisher Site
Abstract
Magnetic slow relaxation is observed in a DyIII-based molecular chain and the magnetic easy-axis is determined via single-crystal magnetometry. Ab initio calculations confirm its orientation and highlight that the latter is governed neither by coordination polyhedron symmetry nor by the chain direction but rather by the single-ion electrostatic environment, a feature that is confirmed by a similar theoretical analysis on other DyIII chains.
Journal
Chemical Communications – Royal Society of Chemistry
Published: Oct 7, 2014