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Metalloporphyrins: their multitalented nature as observed in multi-metal complex systems

Metalloporphyrins: their multitalented nature as observed in multi-metal complex systems Five topics pertaining to the unique chemistry of metalloporphyrins as observed in multi-metal complex systems are introduced. The topics include the following: (i) the unique chromatographic separation of cyclic porphyrins on modified silica gel; (ii) room temperature phosphorescence from the zinc porphyrin part in a zinc porphyrin/rhenium complex hetero dyad; (iii) the substituent effect, in the preparation of a readily soluble special-pair-type zinc porphyrin dimer/rhenium complex having efficient photocatalytic CO2 reduction ability; (iv) assessment of the excited triplet state of a special-pair-type zinc porphyrin dimer in macrocyclic multiporphyrin rings; and (v) solvation/desolvation indicators based on exclusive transformation between the head–head type and head–tail type of supramolecular co-ordination polymers composed of bis(zinc porphyrin)s. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Dalton Transactions Royal Society of Chemistry

Metalloporphyrins: their multitalented nature as observed in multi-metal complex systems

Dalton Transactions , Volume 52 (17): 5 – May 2, 2023

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
1477-9226
eISSN
1477-9234
DOI
10.1039/d2dt04104a
Publisher site
See Article on Publisher Site

Abstract

Five topics pertaining to the unique chemistry of metalloporphyrins as observed in multi-metal complex systems are introduced. The topics include the following: (i) the unique chromatographic separation of cyclic porphyrins on modified silica gel; (ii) room temperature phosphorescence from the zinc porphyrin part in a zinc porphyrin/rhenium complex hetero dyad; (iii) the substituent effect, in the preparation of a readily soluble special-pair-type zinc porphyrin dimer/rhenium complex having efficient photocatalytic CO2 reduction ability; (iv) assessment of the excited triplet state of a special-pair-type zinc porphyrin dimer in macrocyclic multiporphyrin rings; and (v) solvation/desolvation indicators based on exclusive transformation between the head–head type and head–tail type of supramolecular co-ordination polymers composed of bis(zinc porphyrin)s.

Journal

Dalton TransactionsRoyal Society of Chemistry

Published: May 2, 2023

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