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References (7)
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(1975)
Organotransition Metal Chemistry -
W. P. Neumann (1970)
The Organic Chemistry of Tin -
(1985)
The Chemistry of the Metal?Carbon Bond, 2
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(1983)
Current Trends in Organic Synthesis -
(1976)
Transition Metal Organometallics in Organic Synthesis, 1
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(1978)
Aspects of Mechanisms in Organometallic Chemistry -
G. H. Posner (1980)
An Introduction to Synthesis Using Organocopper Reagents
- Publisher
- Wiley
- Copyright
- "Copyright © 1986 Wiley Subscription Services, Inc., A Wiley Company"
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- DOI
- 10.1002/anie.198605081
- Publisher site
- See Article on Publisher Site
Abstract
The cross‐coupling of organotin reagents with a variety of organic electrophiles, catalyzed by palladium, provides a novel method for generating a carbon‐carbon bond. Because this mild, versatile reaction is tolerant of a wide variety of functional groups on either coupling partner, is stereospecific and regioselective, and gives high yields of product, it is ideal for use in the synthesis of elaborate organic molecules. When the coupling reaction is carried out in the presence of carbon monoxide, instead of a direct coupling, carbon monoxide insertion takes place, stitching the two coupling partners together and generating a ketone.
Journal
Angewandte Chemie International Edition – Wiley
Published: Jun 1, 1986
Keywords: ; ; ; ; ; ;