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References (10)
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F. Švec, H. Hrudková, D. Horák, J. Kálal (1977)
Reactive polymers. VIII. Reaction of the epoxide groups of the copolymer glycidyl methacrylate – ethylenedimethacrylate with aliphatic amino compoundsAngewandte Makromolekulare Chemie, 63
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Chemical transformations of polymers. III. Selective hydrolysis of a copolymer of diethylene glycol methacrylate and diethylene glycol dimethacrylateCollection of Czechoslovak Chemical Communications, 31
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Reaktive Polymere. II. Die Herstellung von Metallchelaten vernetzter PolymererAngewandte Makromolekulare Chemie, 49
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F. Švec, D. Horák, J. Kálal (1977)
Reactive polymers. IX. Preparation of macroporous chelate-forming resins from the copolymer glycidyl methacrylate – ethylenedimethacrylate containing iminodiacetic groups†Angewandte Makromolekulare Chemie, 63
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F. Long, J. Pritchard (1956)
Hydrolysis of Substituted Ethylene Oxides in H2O18 Solutions1Journal of the American Chemical Society, 78
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Entropies of Activation and Mechanism for the Acid-catalyzed Hydrolysis of Ethylene Oxide and its Derivatives1Journal of the American Chemical Society, 79
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- Publisher
- Wiley
- Copyright
- Copyright © 1977 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 0959-8103
- eISSN
- 1097-0126
- DOI
- 10.1002/pi.4980090313
- Publisher site
- See Article on Publisher Site
Abstract
Hydrolysis of the epoxide groups of the copolymer glycidylmethacrylate ‐ ethylenedi‐methacrylate in variously concentrated sulphuric acid solutions was studied. An approximate activation energy of hydrolysis, 41 kJ mol−1, was determined from the temperature dependences. For the sake of comparison the effect of pH on the degree of hydrolysis over the whole range of pH values was examined, and the importance of the results with respect to other reactions of the copolymer used was discussed.
Journal
Polymer International – Wiley
Published: Sep 1, 1977