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References (67)
-
Jaturong Jitputti, B. Kitiyanan, P. Rangsunvigit, Kunchana Bunyakiat, L. Attanatho, P. Jenvanitpanjakul (2006)
Transesterification of crude palm kernel oil and crude coconut oil by different solid catalystsChemical Engineering Journal, 116
-
S. Kahraman, M. Önal, Y. Sarikaya, Ihsan Bozdogan (2005)
Characterization of silica polymorphs in kaolins by X-ray diffraction before and after phosphoric acid digestion and thermal treatmentAnalytica Chimica Acta, 552
-
K. Pathak, K. Reddy, N. Bakhshi, A. Dalai (2010)
Catalytic conversion of glycerol to value added liquid productsApplied Catalysis A-general, 372
-
Dora López, J. Goodwin, D. Bruce, S. Furuta (2008)
ESTERIFICATION AND TRANSESTERIFICATION USING MODIFIED-ZIRCONIA CATALYSTSApplied Catalysis A-general, 339
-
K. Wilson, A. Lee, D. Macquarrie, J. Clark (2002)
Structure and reactivity of sol-gel sulphonic acid silicasApplied Catalysis A-general, 228
-
M. Popova, A. Ristić, K. Lazar, Darja Maučec, M. Vassileva, Nataša Novak Tušar (2013)
Iron‐Functionalized Silica Nanoparticles as a Highly Efficient Adsorbent and Catalyst for Toluene Oxidation in the Gas PhaseChemCatChem, 5
-
Shanhui Zhu, Yulei Zhu, Xiaoqing Gao, Tao Mo, Yifeng Zhu, Yong-wang Li (2013)
Production of bioadditives from glycerol esterification over zirconia supported heteropolyacids.Bioresource technology, 130
-
N. Tušar, A. Ristić, G. Mali, M. Mazaj, I. Arčon, D. Arčon, V. Kaučič, N. Logar (2010)
MnO(x) nanoparticles supported on a new mesostructured silicate with textural porosity.Chemistry, 16 19
-
J. Ni, F. Meunier (2007)
Esterification of free fatty acids in sunflower oil over solid acid catalysts using batch and fixed bed-reactorsApplied Catalysis A-general, 333
-
R. Luque, C. Lin, K. Wilson, J. Clark (2016)
Handbook of biofuels production: processes and technologies -
R. Luque, J. Clark (2011)
Biodiesel‐Like Biofuels from Simultaneous Transesterification/Esterification of Waste Oils with a Biomass‐Derived Solid Acid CatalystChemCatChem, 3
-
J. Clark, V. Budarin, Thomas Dugmore, R. Luque, D. Macquarrie, V. Strelko (2008)
Catalytic performance of carbonaceous materials in the esterification of succinic acidCatalysis Communications, 9
-
M. Khayoon, B. Hameed (2011)
Acetylation of glycerol to biofuel additives over sulfated activated carbon catalyst.Bioresource technology, 102 19
-
M. Popova, A. Ristić, M. Mazaj, Darja Maučec, M. Dimitrov, N. Tušar (2014)
Autoreduction of Copper on Silica and Iron‐Functionalized Silica Nanoparticles with Interparticle MesoporosityChemCatChem, 6
-
M. Chidambaram, C. Venkatesan, A. Singh (2006)
Organosilanesulfonic acid-functionalized Zr-TMS catalysts : Synthesis, characterization and catalytic applications in condensation reactionsApplied Catalysis A-general, 310
-
F. Frusteri, F. Arena, G. Bonura, C. Cannilla, L. Spadaro, O. Blasi (2009)
Catalytic etherification of glycerol by tert-butyl alcohol to produce oxygenated additives for diesel fuelApplied Catalysis A-general, 367
-
P. Ferreira, I. Fonseca, A. Ramos, J. Vital, J. Castanheiro (2009)
Glycerol acetylation over dodecatungstophosphoric acid immobilized into a silica matrix as catalystApplied Catalysis B-environmental, 91
-
P. Ferreira, I. Fonseca, A. Ramos, J. Vital, J. Castanheiro (2011)
Acetylation of glycerol over heteropolyacids supported on activated carbonCatalysis Communications, 12
-
V. Deshmane, Y. Adewuyi (2012)
Synthesis of thermally stable, high surface area, nanocrystalline mesoporous tetragonal zirconium dioxide (ZrO2): Effects of different process parametersMicroporous and Mesoporous Materials, 148
-
E. Yoda, Ayako Ootawa (2009)
Dehydration of glycerol on H-MFI zeolite investigated by FT-IRApplied Catalysis A-general, 360
-
F. Lónyi, J. Valyon, J. Engelhardt, F. Mizukami (1996)
Characterization and Catalytic Properties of Sulfated ZrO2–TiO2Mixed OxidesJournal of Catalysis, 160
-
Lianguang Wang, Qun Liu, Minghao Zhou, G. Xiao (2012)
Synthesis of glycerin triacetate over molding zirconia-loaded sulfuric acid catalystJournal of Natural Gas Chemistry, 21
-
M. Testa, V. Parola, L. Liotta, A. Venezia (2013)
Screening of different solid acid catalysts for glycerol acetylationJournal of Molecular Catalysis A-chemical, 367
-
Paul Smith, Y. Ngothai, Q. Nguyen, B. O'Neill (2010)
Improving the low-temperature properties of biodiesel: Methods and consequencesRenewable Energy, 35
-
Biju Devassy, G. Shanbhag, S. Halligudi (2006)
Phenol tert-butylation over zirconia-supported 12-molybdophosphoric acid catalystJournal of Molecular Catalysis A-chemical, 247
-
Kaewta Suwannakarn, E. Lotero, J. Goodwin, Changqing Lu (2008)
Stability of sulfated zirconia and the nature of the catalytically active species in the transesterification of triglyceridesJournal of Catalysis, 255
-
C. Garcia, Sérgio Teixeira, L. Marciniuk, U. Schuchardt (2008)
Transesterification of soybean oil catalyzed by sulfated zirconia.Bioresource technology, 99 14
-
Hui Liu, Lingyan Su, Feifei Liu, Cui Li, Ugwuh Solomon (2011)
Cinder supported K2CO3 as catalyst for biodiesel productionApplied Catalysis B-environmental, 106
-
I. Rodríguez, Corentin Adriany, E. Gaigneaux (2011)
Glycerol acetylation on sulphated zirconia in mild conditionsCatalysis Today, 167
-
A. Kiss, A. Dimian, G. Rothenberg (2006)
Solid acid catalysts for biodiesel production - towards sustainable energyActa Crystallographica Section B-structural Science
-
C. Lin, Lucie Pfaltzgraff, Lorenzo Herrero-Davila, E. Mubofu, Solhy Abderrahim, J. Clark, A. Koutinas, N. Kopsahelis, K. Stamatelatou, F. Dickson, S. Thankappan, Zahouily Mohamed, R. Brocklesby, R. Luque (2013)
Food waste as a valuable resource for the production of chemicals, materials and fuels. Current situation and global perspectiveEnergy and Environmental Science, 6
-
D. Pérez-Quintanilla, Alfredo Sánchez, I. Hierro, M. Fajardo, I. Sierra (2007)
Preparation, characterization, and Zn(2+) adsorption behavior of chemically modified MCM-41 with 5-mercapto-1-methyltetrazole.Journal of colloid and interface science, 313 2
-
A. Sassi, J. Sommer (1999)
Isomerization and cracking reactions of branched octanes on sulfated zirconiaApplied Catalysis A-general, 188
-
C. Zhou, C. Zhou, J. Beltramini, Yong-xian Fan, G. Lu (2008)
Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals.Chemical Society reviews, 37 3
-
R. Barthos, F. Lónyi, J. Engelhardt, J. Valyon (2000)
A study of the acidic and catalytic properties of pure and sulfated zirconia–titania and zirconia–silica mixed oxidesTopics in Catalysis, 10
-
M. Khayoon, M. Olutoye, B. Hameed (2012)
Utilization of crude karanj (Pongamia pinnata) oil as a potential feedstock for the synthesis of fatty acid methyl esters.Bioresource technology, 111
-
Shanhui Zhu, Xiaoqing Gao, Fang Dong, Yulei Zhu, Hongyan Zheng, Yong-wang Li (2013)
Design of a highly active silver-exchanged phosphotungstic acid catalyst for glycerol esterification with acetic acidJournal of Catalysis, 306
-
M. Gracia, A. Balu, J. Campelo, R. Luque, J. Marinas, A. Romero (2009)
Evidences of the in situ generation of highly active Lewis acid species on Zr-SBA-15Applied Catalysis A-general, 371
-
Arne Bienholz, H. Hofmann, P. Claus (2011)
Selective hydrogenolysis of glycerol over copper catalysts both in liquid and vapour phase: Correlation between the copper surface area and the catalyst's activityApplied Catalysis A-general, 391
-
W. Li, Kenzo Oshihara, W. Ueda (1999)
Catalytic performance for propane selective oxidation and surface properties of 12-molybdophosphoric acid treated with pyridineApplied Catalysis A-general, 182
-
K. Jagadeeswaraiah, M. Balaraju, P. Prasad, N. Lingaiah (2010)
Selective esterification of glycerol to bioadditives over heteropoly tungstate supported on Cs-containing zirconia catalystsApplied Catalysis A-general, 386
-
M. Balaraju, P. Nikhitha, K. Jagadeeswaraiah, K. Srilatha, P. Prasad, N. Lingaiah (2010)
Acetylation of glycerol to synthesize bioadditives over niobic acid supported tungstophosphoric acid catalystsFuel Processing Technology, 91
-
Jiabo Li, Tao Wang (2010)
Coupling reaction and azeotropic distillation for the synthesis of glycerol carbonate from glycerol and dimethyl carbonateChemical Engineering and Processing, 49
-
E. Barrett, L. Joyner, Paul Halenda (1951)
(CONTRIBUTION FROM THE MULTIPLE FELLOWSHIP OF BAUGH AND SONS COMPANY, MELLOX INSTITUTE) The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms -
M. Akçay (2005)
The surface acidity and characterization of Fe-montmorillonite probed by in situ FT-IR spectroscopy of adsorbed pyridineApplied Catalysis A-general, 294
-
S. Sing, R. Everett, L. Haul, Netherlands Moscou, R. Pierotti, J. Rouquerol, France, T. Siemieniewska
International Union of Pure and Applied Chemistry Physical Chemistry Division Commission on Colloid and Surface Chemistry including Catalysis* Reporting Physisorption Data for Gas/solid Systems with Special Reference to the Determination of Surface Area and Porosity Reporting Physisorption Data for -
Julián Sánchez, Diana Hernández, Jorge Moreno, F. Mondragón, Jhon Fernández (2011)
Alternative carbon based acid catalyst for selective esterification of glycerol to acetylglycerolsApplied Catalysis A-general, 405
-
E. Li, Z. Xu, V. Rudolph (2009)
MgCoAl–LDH derived heterogeneous catalysts for the ethanol transesterification of canola oil to biodieselApplied Catalysis B-environmental, 88
-
M. Trejda, Katarzyna Stawicka, M. Ziolek (2011)
New catalysts for biodiesel additives productionApplied Catalysis B-environmental, 103
-
W. Hua, Y. Yue, Z. Gao (2001)
Acidity enhancement of SBA mesoporous molecular sieve by modification with SO42−/ZrO2Journal of Molecular Catalysis A-chemical, 170
-
T. Peters, N. Benes, A. Holmen, J. Keurentjes (2006)
Comparison of commercial solid acid catalysts for the esterification of acetic acid with butanolApplied Catalysis A-general, 297
-
G. Yadav, J. Nair (1999)
Sulfated zirconia and its modified versions as promising catalysts for industrial processesMicroporous and Mesoporous Materials, 33
-
R. Gore, W. Thomson (1998)
Pulsed gas-phase alkylation of isobutane/2-butene over sulfated zirconiaApplied Catalysis A-general, 168
-
D. Liang, Jing Gao, Hui Sun, Pin Chen, Z. Hou, Xiaoming Zheng (2011)
Selective oxidation of glycerol with oxygen in a base-free aqueous solution over MWNTs supported Pt catalystsApplied Catalysis B-environmental, 106
-
S. Shylesh, Sahida Sharma, S. Mirajkar, Avninder Singh (2004)
Silica functionalised sulphonic acid groups: synthesis, characterization and catalytic activity in acetalization and acetylation reactionsJournal of Molecular Catalysis A-chemical, 212
-
P. Ferreira, I. Fonseca, A. Ramos, J. Vital, J. Castanheiro (2009)
Esterification of glycerol with acetic acid over dodecamolybdophosphoric acid encaged in USY zeoliteCatalysis Communications, 10
-
C. Zhou, Heng-yu Zhao, D. Tong, L. Wu, W. Yu (2013)
Recent Advances in Catalytic Conversion of GlycerolCatalysis Reviews, 55
-
S. Chokkaram, B. Davis (1997)
Dehydration of 2-octanol over zirconia catalysts: Influence of crystal structure, sulfate addition and pretreatmentJournal of Molecular Catalysis A-chemical, 118
-
V. Deshmane, Y. Adewuyi (2013)
Mesoporous nanocrystalline sulfated zirconia synthesis and its application for FFA esterification in oilsApplied Catalysis A-general, 462
-
R. Grieken, J. Melero, G. Morales (2005)
Fries rearrangement of phenyl acetate over sulfonic modified mesostructured SBA-15 materialsApplied Catalysis A-general, 289
-
Q. Xia, K. Hidajat, S. Kawi (2002)
Effect of ZrO2 Loading on the Structure, Acidity, and Catalytic Activity of the SO42−/ZrO2/MCM-41 Acid CatalystJournal of Catalysis, 205
-
Valter Gonçalves, Bianca Pinto, J. Silva, C. Mota (2008)
Acetylation of glycerol catalyzed by different solid acidsCatalysis Today, 133
-
S. Brunauer, P. Emmett, E. Teller (1938)
ADSORPTION OF GASES IN MULTIMOLECULAR LAYERSJournal of the American Chemical Society, 60
-
J. Iglesias, M. Gracia, R. Luque, A. Romero, J. Melero (2012)
Maximizing the Accessibility of Active Species in Weakly Acidic Zr‐SBA‐15 MaterialsChemCatChem, 4
-
A. Corma, G. Huber, L. Sauvanaud, P. O'connor (2008)
Biomass to chemicals : Catalytic conversion of glycerol/water mixtures into acrolein, reaction networkJournal of Catalysis, 257
-
T. Borrego, M. Andrade, M. Pinto, Ana Silva, A. Carvalho, J. Rocha, C. Freire, J. Pires (2010)
Physicochemical characterization of silylated functionalized materials.Journal of colloid and interface science, 344 2
-
Pankaj Sharma, Anjali Patel (2009)
Zirconia supported 12-molybdophosphoric acid: Physico-chemical characterization and non-solvent liquid phase oxidation of styreneApplied Surface Science, 255
- Publisher
- Royal Society of Chemistry
- Copyright
- This journal is © The Royal Society of Chemistry
- ISSN
- 2044-4753
- eISSN
- 2044-4761
- DOI
- 10.1039/c4cy00548a
- Publisher site
- See Article on Publisher Site
Abstract
Zirconia nanomaterials were prepared by impregnation of KIL-2 type silica with 4, 8 and 12 wt.% ZrO2 and were modified by sulphate groups in order to vary the type and strength of acidity. Samples were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and N2 physisorption methods. Acidic properties of adsorbed pyridine were investigated by FT-IR spectroscopy. The catalytic performance of ZrKIL-2 and SO42−/ZrKIL-2 in glycerol esterification with acetic acid was studied and compared to that of pure zirconia varieties. It was found that silica-supported zirconia samples are more active than pure zirconia ones. With increasing ZrO2 content, KIL-2-supported catalysts showed increasing catalytic activity and selectivity in producing valuable fuel additives, di- and triacetyl glycerols. Sulphated analogues showed even higher activity and selectivity compared to non-sulphated ones due to their strong Brönsted acidity.
Journal
Catalysis Science & Technology – Royal Society of Chemistry
Published: Oct 6, 2014