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Synthesis of Macrocyclic Poly(ε‐caprolactone) by Intramolecular Cross‐Linking of Unsaturated End Groups of Chains Precyclic by the Initiation

Synthesis of Macrocyclic Poly(ε‐caprolactone) by Intramolecular Cross‐Linking of Unsaturated End... Biodegradable cyclic polyesters are synthesized by using an ε‐caprolactone polymerization initiated by a cyclic tin alkoxide, followed by the addition and sequential polymerization of a few units of α‐(1‐acryloxyethyl)‐ε‐caprolactone. Tadpole‐shaped polyesters with two tails of controllable length are readily prepared by this procedure (see picture). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Angewandte Chemie International Edition Wiley

Synthesis of Macrocyclic Poly(ε‐caprolactone) by Intramolecular Cross‐Linking of Unsaturated End Groups of Chains Precyclic by the Initiation

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References (9)

Publisher
Wiley
Copyright
Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1433-7851
eISSN
1521-3773
DOI
10.1002/anie.200503961
pmid
16518775
Publisher site
See Article on Publisher Site

Abstract

Biodegradable cyclic polyesters are synthesized by using an ε‐caprolactone polymerization initiated by a cyclic tin alkoxide, followed by the addition and sequential polymerization of a few units of α‐(1‐acryloxyethyl)‐ε‐caprolactone. Tadpole‐shaped polyesters with two tails of controllable length are readily prepared by this procedure (see picture).

Journal

Angewandte Chemie International EditionWiley

Published: Mar 27, 2006

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