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- Publisher
- Wiley
- Copyright
- Copyright © 2014 Wiley Subscription Services, Inc., A Wiley Company
- eISSN
- 2196-0216
- DOI
- 10.1002/celc.201300074
- Publisher site
- See Article on Publisher Site
Abstract
The thiolate/disulfide organic redox couple (McMT−/BMT), derived from 2‐mercapto‐5‐methyl‐1,3,4‐thiadiazole (McMT), recently proposed as an alternative to usual inorganic couples in dye‐sensitized solar cells, exhibits a remarkable reversibility and stability in a thermogalvanic cell containing a 1‐ethyl‐3‐methyimidazolium tetrafluoroborate/acetonitrile (EMIMBF4/AN) mixture. The thermoelectric power depends strongly on concentrations of both the ionic liquid and the redox couple. It is enhanced by a factor of six at high ionic‐liquid concentrations. The control of these parameters can be used to enhance the thermopower and the thermoelectric efficiency of future ionic‐liquid thermocells.
Journal
ChemElectroChem – Wiley
Published: Nov 11, 2014
Keywords: ; ; ; ;