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(2001)
Pure Polymorph C of Zeolite Beta Synthesized by Using Framework Isomorphous Substitution as a Structure‐Directing Mechanism
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F-: A MULTIFUNCTIONAL TOOL FOR MICROPOROUS SOLIDS a) MINERALIZING, STRUCTURE DIRECTING AND TEMPLATING EFFECTS IN THE SYNTHESIS
Subsitution of germanium for silicon in the preparation of the zeolite Beta allows the synthesis and characterization of a third, heretofore predicted, polymorph “C”; a (001) view is shown in the picture. Germanium preferentially occupies positions in double four‐membered ring cages, the secondary building units of polymorph C, and favors the formation of polymorph C regardless of which of the eight organic structure‐directing agents were used.
Angewandte Chemie International Edition – Wiley
Published: Jan 18, 2001
Keywords: ; ;
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