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Back cover Showcasing research from Professor Yokoi's laboratory, Institute of Biomaterials and Bioengineering, Tokyo Medical As featured in: and Dental University, Tokyo, Japan. Volume 53 Number 34 14 September 2024 Pages 14119-14506 Octacalcium phosphate with incorporated terephthalate ion Dalton derivatives: novel guest molecules and unique fl uorescence Transactions properties An international journal of inorganic chemistry rsc.li/dalton Octacalcium phosphate (OCP) has a layered structure that can incorporate various carboxylic acids, exhibits fl uorescence when aromatic carboxylate ions are present in the interlayers. In this study, we incorporated 4-(carboxymethyl)benzoate and 1,4-phenylenediacetate ions into OCP and investigated the resulting fl uorescence properties. OCP with incorporated 1,4-phenylenediacetate ions showed blue fl uorescence. In ISSN 1477-9226 contrast, OCP with incorporated 4-(carboxymethyl)benzoate PAPER Feng Li et al. Spin crossover of a Fe( II ) mononuclear complex induced by intermolecular factors involving chloride and solvent ordering ions exhibited two-colour fl uorescence, with pink emission and blue emission. These unique fl uorescence characteristics See Taishi Yokoi et al. , Dalton Trans. , combined with the excellent biological properties of OCP can be 2024, 53 , 14163. exploited to develop novel biofriendly fl uorescent probes. rsc.li/dalton Registered charity number: 207890 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Dalton Transactions Royal Society of Chemistry

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Royal Society of Chemistry — Aug 27, 2024

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Abstract

Showcasing research from Professor Yokoi's laboratory, Institute of Biomaterials and Bioengineering, Tokyo Medical As featured in: and Dental University, Tokyo, Japan. Volume 53 Number 34 14 September 2024 Pages 14119-14506 Octacalcium phosphate with incorporated terephthalate ion Dalton derivatives: novel guest molecules and unique fl uorescence Transactions properties An international journal of inorganic chemistry rsc.li/dalton Octacalcium phosphate (OCP) has a layered structure that can incorporate various carboxylic acids, exhibits fl uorescence when aromatic carboxylate ions are present in the interlayers. In this study, we incorporated 4-(carboxymethyl)benzoate and 1,4-phenylenediacetate ions into OCP and investigated the resulting fl uorescence properties. OCP with incorporated 1,4-phenylenediacetate ions showed blue fl uorescence. In ISSN 1477-9226 contrast, OCP with incorporated 4-(carboxymethyl)benzoate PAPER Feng Li et al. Spin crossover of a Fe( II ) mononuclear complex induced by intermolecular factors involving chloride and solvent ordering ions exhibited two-colour fl uorescence, with pink emission and blue emission. These unique fl uorescence characteristics See Taishi Yokoi et al. , Dalton Trans. , combined with the excellent biological properties of OCP can be 2024, 53 , 14163. exploited to develop novel biofriendly fl uorescent probes. rsc.li/dalton Registered charity number: 207890

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Dalton TransactionsRoyal Society of Chemistry

Published: Aug 27, 2024

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