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Spin-orbital phase diagram of perovskite-type R VO 3 ( R = rare -earth ion or Y)

Spin-orbital phase diagram of perovskite-type R VO 3 ( R = rare -earth ion or Y) The global phase diagram for the spin and orbital ordering has been investigated for perovskite-type R VO 3 ( R being a rare-earth ion or Y) by measurements of specific heat, magnetization, and Raman-scattering spectra. R VO 3 ( R = Lu - Pr ) , in which the large tilting of VO 6 tends to stabilize the collective Jahn-Teller distortion, shows a structural phase transition concomitantly with the G -type orbital ordering (OO) at a temperature far above the C -type magnetic transition temperature. By contrast the C -type spin correlation appears to develop primarily and then induce the G -type OO in CeVO 3 and LaVO 3 with smaller lattice distortion. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Physical Review B American Physical Society (APS)

Spin-orbital phase diagram of perovskite-type R VO 3 ( R = rare -earth ion or Y)

Physical Review B , Volume 68 (10) – Sep 1, 2003
4 pages

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Publisher
American Physical Society (APS)
Copyright
Copyright © 2003 The American Physical Society
ISSN
1095-3795
DOI
10.1103/PhysRevB.68.100406
Publisher site
See Article on Publisher Site

Abstract

The global phase diagram for the spin and orbital ordering has been investigated for perovskite-type R VO 3 ( R being a rare-earth ion or Y) by measurements of specific heat, magnetization, and Raman-scattering spectra. R VO 3 ( R = Lu - Pr ) , in which the large tilting of VO 6 tends to stabilize the collective Jahn-Teller distortion, shows a structural phase transition concomitantly with the G -type orbital ordering (OO) at a temperature far above the C -type magnetic transition temperature. By contrast the C -type spin correlation appears to develop primarily and then induce the G -type OO in CeVO 3 and LaVO 3 with smaller lattice distortion.

Journal

Physical Review BAmerican Physical Society (APS)

Published: Sep 1, 2003

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