Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/countersolvent-electrolytes-for-lithium-metal-batteries-XbsTIkTVNS
References (36)
-
Junmei Wang, Wei Wang, P. Kollman, D. Case (2006)
Automatic atom type and bond type perception in molecular mechanical calculations.Journal of molecular graphics & modelling, 25 2
-
Dingchang Lin, Yayuan Liu, Yi Cui (2017)
Reviving the lithium metal anode for high-energy batteries.Nature nanotechnology, 12 3
-
Yuki Yamada, Jianhui Wang, Seongjae Ko, Eriko Watanabe, A. Yamada (2019)
Publisher Correction: Advances and issues in developing salt-concentrated battery electrolytesNature Energy, 4
-
Jianming Zheng, M. Engelhard, Donghai Mei, Shuhong Jiao, B. Polzin, Ji‐Guang Zhang, Wu Xu (2017)
Electrolyte additive enabled fast charging and stable cycling lithium metal batteriesNature Energy, 2
-
Shuru Chen, Jianming Zheng, Donghai Mei, K. Han, M. Engelhard, Wengao Zhao, Wu Xu, Jun Liu, Ji‐Guang Zhang (2018)
High‐Voltage Lithium‐Metal Batteries Enabled by Localized High‐Concentration ElectrolytesAdvanced Materials, 30
-
W. Humphrey, A. Dalke, K. Schulten (1996)
VMD: visual molecular dynamics.Journal of molecular graphics, 14 1
-
Xue‐Qiang Zhang, Xiang Chen, Xin‐Bing Cheng, Bo‐Quan Li, Xin Shen, Chong Yan, Jiaqi Huang, Qiang Zhang (2018)
Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes.Angewandte Chemie, 57 19
-
Jianhui Wang, Yuki Yamada, Keitaro Sodeyama, C. Chiang, Y. Tateyama, A. Yamada (2016)
Superconcentrated electrolytes for a high-voltage lithium-ion batteryNature Communications, 7
-
S. Plimpton (1993)
Fast parallel algorithms for short-range molecular dynamicsJournal of Computational Physics, 117
-
Nianwu Li, Ya‐Xia Yin, Chunpeng Yang, Yu‐Guo Guo (2016)
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal AnodesAdvanced Materials, 28
-
Yayuan Liu, Dingchang Lin, Zheng Liang, Jie Zhao, Kai Yan, Yi Cui (2016)
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anodeNature Communications, 7
-
Crystallogr -
Jie Zhao, Lei Liao, Feifei Shi, Ting Lei, Guangxu Chen, Allen Pei, Jie Sun, Kai Yan, Guangmin Zhou, Jin Xie, Chong Liu, Yuzhang Li, Zheng Liang, Z. Bao, Yi Cui (2017)
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability.Journal of the American Chemical Society, 139 33
-
Xiao Liang, Q. Pang, Ivan Kochetkov, Marina Sempere, He Huang, Xiaoqi Sun, L. Nazar (2017)
A facile surface chemistry route to a stabilized lithium metal anodeNature Energy, 2
-
Jianming Zheng, J. Lochala, A. Kwok, Z. Deng, Jie Xiao (2017)
Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage ApplicationsAdvanced Science, 4
-
Muqin Wang, Liyuan Huai, Guohong Hu, Guohong Hu, Shan Yang, F. Ren, F. Ren, Shuwei Wang, Zhenggang Zhang, Zhenlian Chen, Zhe Peng, Cai Shen, Wang Deyu (2018)
Effect of LiFSI Concentrations To Form Thickness- and Modulus-Controlled SEI Layers on Lithium Metal AnodesJournal of Physical Chemistry C, 122
-
K. Shimizu, D. Almantariotis, M. Gomes, A. Pádua, J. Lopes (2010)
Molecular force field for ionic liquids v: hydroxyethylimidazolium, dimethoxy-2- methylimidazolium, and fluoroalkylimidazolium cations and bis(fluorosulfonyl)amide, perfluoroalkanesulfonylamide, and fluoroalkylfluorophosphate anions.The journal of physical chemistry. B, 114 10
-
T. Doi, Y. Shimizu, M. Hashinokuchi, M. Inaba (2017)
Dilution of Highly Concentrated LiBF4/Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi0.5Mn1.5O4 Positive ElectrodesJournal of The Electrochemical Society, 164
-
A. Jakalian, D. Jack, C. Bayly (2002)
Fast, efficient generation of high‐quality atomic charges. AM1‐BCC model: II. Parameterization and validationJournal of Computational Chemistry, 23
-
Lu Yu, Shuru Chen, Hongkyung Lee, Linchao Zhang, M. Engelhard, Qiuyan Li, Shuhong Jiao, Jun Liu, Wu Xu, Ji‐Guang Zhang (2018)
A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal BatteriesACS Energy Letters
-
Qinglin Zhang, Jie Pan, Peng Lu, Zhongyi Liu, M. Verbrugge, B. Sheldon, Yang-Tse Cheng, Y. Qi, Xingcheng Xiao (2016)
Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries.Nano letters, 16 3
-
Dingchang Lin, Yayuan Liu, Zheng Liang, Hyun‐Wook Lee, Jie Sun, Haotian Wang, Kai Yan, Jin Xie, Yi Cui (2016)
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes.Nature nanotechnology, 11 7
-
F. Huang, Guoqiang Ma, Z. Wen, Jun Jin, Shiqing Xu, Junjie Zhang (2018)
Enhancing metallic lithium battery performance by tuning the electrolyte solution structureJournal of Materials Chemistry, 6
-
Xue‐Qiang Zhang, Xiang Chen, Li-Peng Hou, Bo‐Quan Li, Xin‐Bing Cheng, Jiaqi Huang, Qiang Zhang (2019)
Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal BatteriesACS Energy Letters
-
K. Momma, F. Izumi (2011)
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology dataJournal of Applied Crystallography, 44
-
Xiaodi Ren, Shuru Chen, Hongkyung Lee, Donghai Mei, M. Engelhard, S. Burton, Wengao Zhao, Jianming Zheng, Qiuyan Li, M. Ding, M. Schroeder, J. Alvarado, K. Xu, Y. Meng, Jun Liu, Ji‐Guang Zhang, Wu Xu (2018)
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal BatteriesChem
-
Chaojiang Niu, Hongkyung Lee, Shuru Chen, Qiuyan Li, J. Du, Wu Xu, Ji‐Guang Zhang, M. Whittingham, Jie Xiao, Jun Liu (2019)
High-energy lithium metal pouch cells with limited anode swelling and long stable cyclesNature Energy, 4
-
Jun Liu, Zhenan Bao, Yi Cui, Eric Dufek, J. Goodenough, P. Khalifah, Qiuyan Li, B. Liaw, Ping Liu, A. Manthiram, Y. Meng, V. Subramanian, M. Toney, V. Viswanathan, M. Whittingham, Jie Xiao, Wu Xu, Jihui Yang, Xiao‐Qing Yang, Ji‐Guang Zhang (2019)
Pathways for practical high-energy long-cycling lithium metal batteriesNature Energy, 4
-
Liumin Suo, Yong‐Sheng Hu, Hong Li, M. Armand, Liquan Chen (2013)
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteriesNature Communications, 4
-
Jing Zheng, G. Ji, Xiulin Fan, Ji Chen, Qin Li, Haiyang Wang, Yong Yang, Kerry Demella, S. Raghavan, Chunsheng Wang (2019)
High‐Fluorinated Electrolytes for Li–S BatteriesAdvanced Energy Materials, 9
-
Xiulin Fan, Long Chen, Xiao Ji, T. Deng, S. Hou, Ji Chen, Jing Zheng, Fei Wang, Jianjun Jiang, K. Xu, Chunsheng Wang (2018)
Highly Fluorinated Interphases Enable High-Voltage Li-Metal BatteriesChem, 4
-
A. Jakalian, B. Bush, D. Jack, C. Bayly (2000)
Fast, efficient generation of high‐quality atomic charges. AM1‐BCC model: I. MethodJournal of Computational Chemistry, 21
-
Long Chen, Xiulin Fan, E. Hu, Xiao Ji, Ji Chen, S. Hou, T. Deng, Jing Li, D. Su, Xiao‐Qing Yang, Chunsheng Wang (2019)
Achieving High Energy Density through Increasing the Output Voltage: A Highly Reversible 5.3 V BatteryChem
-
Feilong Qiu, Xiang Li, Han Deng, Di Wang, Xiaowei Mu, P. He, Haoshen Zhou (2018)
A Concentrated Ternary‐Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess LiAdvanced Energy Materials, 9
-
Jiangfeng Qian, W. Henderson, Wu Xu, P. Bhattacharya, M. Engelhard, O. Borodin, Ji‐Guang Zhang (2015)
High rate and stable cycling of lithium metal anodeNature Communications, 6
-
J. Katon, M. Cohen (1975)
The Vibrational Spectra and Structure of Dimethyl Carbonate and its Conformational BehaviorCanadian Journal of Chemistry, 53
- Publisher
- Wiley
- Copyright
- © 2020 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1614-6832
- eISSN
- 1614-6840
- DOI
- 10.1002/aenm.201903568
- Publisher site
- See Article on Publisher Site
Abstract
Development of electrolytes that simultaneously have high ionic conductivity, wide electrochemical window, and lithium dendrite suppression ability is urgently required for high‐energy lithium‐metal batteries (LMBs). Herein, an electrolyte is designed by adding a countersolvent into LiFSI/DMC (lithium bis(fluorosulfonyl)amide/dimethyl carbonate) electrolytes, forming countersolvent electrolytes, in which the countersolvent is immiscible with the salt but miscible with the carbonate solvents. The solvation structure and unique properties of the countersolvent electrolyte are investigated by combining electroanalytical technology with a Molecular Dynamics simulation. Introducing the countersolvent alters the coordination shell of Li+ cations and enhances the interaction between Li+ cations and FSI− anions, which leads to the formation of a LiF‐rich solid electrolyte interphase, arising from the preferential reduction of FSI− anions. Notably, the countersolvent electrolyte suppresses Li dendrites and enables stable cycling performance of a Li||NCM622 battery at a high cut‐off voltage of 4.6 V at both 25 and 60 °C. This study provides an avenue to understand and design electrolytes for high‐energy LMBs in the future.
Journal
Advanced Energy Materials – Wiley
Published: Mar 1, 2020
Keywords: ; ; ;