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- Publisher
- Wiley
- Copyright
- Copyright © 1993 Wiley Subscription Services
- ISSN
- 0951-4198
- eISSN
- 1097-0231
- DOI
- 10.1002/rcm.1290070506
- Publisher site
- See Article on Publisher Site
Abstract
Deprotonated allyl alcohol undergoes collision‐induced losses of H2, CH2O and C2H4 with minor hydrogen randomization occurring prior to or during these dissociations. A further fragmentation involves loss of methane: labelling studies (with CH2CHCD2O−) suggest that this loss is preceded by the equilibration CH2CHCD2O− ⇌ CD2CHCH2O−. The methyl homologues of allyl alcohol form isomeric C3H 5− ions: the charge reversal spectra of these isomers confirm that CH2CHCH 2−, CH2C̄CMe and HC̄CHMe are separate species, and also suggest that all three of the corresponding positive ions are formed on the charge‐reversal time‐scale.
Journal
Rapid Communications in Mass Spectrometry – Wiley
Published: Jan 1, 1993