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An extra layer of complexity

An extra layer of complexity Strong interactions between oxide supports and catalytic metal particles can lead to inhibitive oxide layers forming over the active metal catalyst. Now, adsorbate-induced metal–support interactions have been shown to lead to a porous overlayer in the Rh/TiO2 system that tunes catalyst activity, improving its selectivity for the partial reduction of CO2. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Nature Chemistry Springer Journals

An extra layer of complexity

Nature Chemistry , Volume 9 (2) – Jan 24, 2017

An extra layer of complexity

HCO HCO news & views relationships can also speed up evolution because the protocells were specifically made before. Or maybe we are again too through selective pressures on capture- designed to interact and to transfer cargo. inu fl enced by life as we know it. In other evasion mechanisms . To answer whether similar predatory words, perhaps all that is needed is more Using a system with only a few mechanisms could easily emerge from ingenious chemistry. ❐ molecular components, the team has shown primitive cells or to investigate the effect of how even rudimentary protocells can predator–prey interactions on the evolution Sheref S. Mansy is at the Centre for Integrative interact with each other and potentially of protocells and on the co-dependent Biology, University of Trento, via Sommarive 9, influence evolutionary trajectories. dynamics of the synthetic ecosystem, some 38123 Povo TN, Italy. Furthermore, the acquisition of foreign type of hereditary system needs to be e-mail: [email protected] DNA by the predator, as observed in this incorporated. The most obvious way would References case, is not unlike natural mechanisms seem to be to encode the components 1. Szostak J. W., Bartel D. P. & Luisi P. L. Nature of transformation, transduction and of the protocell within DNA, so that the 409, 387–390 (2001). conjugation, which often confers new transcription–translation of the genome 2. Qiao, Y., Li, M., Booth, R. & Mann, S. Nat. Chem. 9, 110–119 (2017). phenotypes on recipient cells that are of surviving protocells would lead to an 3. Attwater, J. & Holliger, P. Nat. Methods 11, 495–498 (2014). critical for survival (Fig. 1). However, it enrichment of daughter protocells with 4. Oparin A. I. e O Th rigin of Life New York (Macmillan, 1938) must be remembered that what has been selected phenotypes. The problem is that 5. Darimont C. T. et al. Proc. Natl Acad. Sci. USA shown in this synthetic...
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References (8)

Publisher
Springer Journals
Copyright
Copyright © 2017 by Nature Publishing Group, a division of Macmillan Publishers Limited. All Rights Reserved.
Subject
Chemistry; Chemistry/Food Science, general; Analytical Chemistry; Organic Chemistry; Physical Chemistry; Inorganic Chemistry; Biochemistry, general
ISSN
1755-4330
eISSN
1755-4349
DOI
10.1038/nchem.2724
Publisher site
See Article on Publisher Site

Abstract

Strong interactions between oxide supports and catalytic metal particles can lead to inhibitive oxide layers forming over the active metal catalyst. Now, adsorbate-induced metal–support interactions have been shown to lead to a porous overlayer in the Rh/TiO2 system that tunes catalyst activity, improving its selectivity for the partial reduction of CO2.

Journal

Nature ChemistrySpringer Journals

Published: Jan 24, 2017

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