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Abstract
We report a study of the epoxidation of soybean oil and soybean methyl esters with hydrogen peroxide in dilute solution (6 wt%) using an amorphous heterogeneous Ti/SiO catalyst in the presence of -butyl alcohol. The influence of some relevant process variables such as temperature and the hydrogen peroxide-to-double bond molar ratio on performance is examined. The highest yields of epoxidized olefins were obtained upon using a HO∶ substrate molar ratio of 1.1 ∶ 1. Higher ratios than this were not effective for speeding up the reaction. Under the experimental conditions employed in this work, no degradation of the oxirane ring was observed.
Journal
Green Chemistry – Royal Society of Chemistry
Published: Jul 27, 2004