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Chemistry and technology of 2‐alkenyl azlactones

Chemistry and technology of 2‐alkenyl azlactones The chronology of 2‐alkenyl azlactone research at 3M is discussed in terms of its origination; consideration of economics, overall safety, and opportunities for patent protection; elaboration of the chemistry; and, finally, applying lessons learned toward the development of commercial technologies. The chemistry is dominated by the presence of three electrophilic reaction centers and a readily polymerizable 2‐alkenyl group. Technological development has been focused in four general areas: acrylamide monomers, acrylamide materials, azlactone materials, and polymer modification. Application areas disinclude lithographic printing plates, contact lens materials, adhesives, dispersants for printing inks, and supports for immobilizing enzymes. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3655–3677, 2001 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Polymer Science Part A Polymer Chemistry Wiley

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References (26)

Publisher
Wiley
Copyright
Copyright © 2001 Wiley Subscription Services, Inc., A Wiley Company
ISSN
0887-624X
eISSN
1099-0518
DOI
10.1002/pola.10007
Publisher site
See Article on Publisher Site

Abstract

The chronology of 2‐alkenyl azlactone research at 3M is discussed in terms of its origination; consideration of economics, overall safety, and opportunities for patent protection; elaboration of the chemistry; and, finally, applying lessons learned toward the development of commercial technologies. The chemistry is dominated by the presence of three electrophilic reaction centers and a readily polymerizable 2‐alkenyl group. Technological development has been focused in four general areas: acrylamide monomers, acrylamide materials, azlactone materials, and polymer modification. Application areas disinclude lithographic printing plates, contact lens materials, adhesives, dispersants for printing inks, and supports for immobilizing enzymes. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3655–3677, 2001

Journal

Journal of Polymer Science Part A Polymer ChemistryWiley

Published: Jan 1, 2001

Keywords: ; ; ; ; ; ; ;

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