Improvement of Electrochemical Performances of Li [ Ni0.8Co0.1Mn0.1 ] O2 Cathode Materials by Fluorine Substitution
Improvement of Electrochemical Performances of Li [ Ni0.8Co0.1Mn0.1 ] O2 Cathode Materials by...
Woo, S.-U.; Park, B.-C.; Yoon, C. S.; Myung, S.-T.; Prakash, Jai; Sun, Y.-K.
2007-05-11 00:00:00
Layered (, 0.02, 0.04, and 0.06) materials having spherical morphology have been synthesized by a hydroxide coprecipitation method. The effect of fluorine content on the structure, morphology, electrochemical properties, and thermal stability of the has been extensively studied. Electrochemical impedance spectroscopy and electron microscopy showed that fluorine substitution played the important role of reducing the interfacial resistance between cathode and electrolyte, resulting from stabilization of the host structure. The fluorine substitution for oxygen substantially improved the overall electrochemical properties of , such as the capacity retention, rate capability, and thermal stability.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngJournal of the Electrochemical SocietyIOP Publishinghttp://www.deepdyve.com/lp/iop-publishing/improvement-of-electrochemical-performances-of-li-ni0-8co0-1mn0-1-o2-q4barHuEUC
Improvement of Electrochemical Performances of Li [ Ni0.8Co0.1Mn0.1 ] O2 Cathode Materials by Fluorine Substitution
Layered (, 0.02, 0.04, and 0.06) materials having spherical morphology have been synthesized by a hydroxide coprecipitation method. The effect of fluorine content on the structure, morphology, electrochemical properties, and thermal stability of the has been extensively studied. Electrochemical impedance spectroscopy and electron microscopy showed that fluorine substitution played the important role of reducing the interfacial resistance between cathode and electrolyte, resulting from stabilization of the host structure. The fluorine substitution for oxygen substantially improved the overall electrochemical properties of , such as the capacity retention, rate capability, and thermal stability.
Journal
Journal of the Electrochemical Society
– IOP Publishing
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