Zirconia-silica mesoporous powders act as very efficient heterogeneous catalysts for both alkyne hydroformylation and Pauson-Khand reaction and yield regioselectivities opposite to those usually observed.
Bernard and, H. Alper (1999)
Regioselective Hydroformylation of Enynes Catalyzed by a Zwitterionic Rhodium Complex and Triphenyl PhosphiteJournal of Organic Chemistry, 64
S. Gibson, S. Lewis, N. Mainolfi (2004)
Transition metal-mediated routes to cyclopentenonesJournal of Organometallic Chemistry, 689
R. Hutchins, B. Maryanoff, Cynthia Milewski (1971)
Selective reduction of aliphatic ketones and aldehydes to hydrocarbons with sodium cyanoborohydride and p-toluenesulfonyl hydrazide in dimethylformamide-sulfolaneJournal of the American Chemical Society, 93
Bernard and, H. Alper (1999)
The First Regioselective Hydroformylation of Acetylenic Thiophenes Catalyzed by a Zwitterionic Rhodium Complex and Triphenyl PhosphiteJournal of Organic Chemistry, 64
A. Corma (1997)
From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis.Chemical reviews, 97 6
Chun-fang Huo, Yong-wang Li, M. Beller, H. Jiao (2005)
Hydroformylation and isomerization of allene and propyne: a density functional theory study.Chemistry, 11 3
Tamotsu Takahashi, Z. Xi, Akiko Yamazaki, Yuanhong Liu, K. Nakajima, M. Kotora (1998)
Cycloaddition Reaction of Zirconacyclopentadienes to Alkynes: Highly Selective Formation of Benzene Derivatives from Three Different AlkynesJournal of the American Chemical Society, 120
A. Taguchi, F. Schüth (2005)
Ordered mesoporous materials in catalysisMicroporous and Mesoporous Materials, 77
Audrey Moores, N. Mézailles, L. Ricard, P. Floch (2005)
η5-Rhodium(I) Complexes of a λ4-Phosphinine Anion: Syntheses, X-ray Crystal Structures, and Application in the Catalyzed Hydroformylation of OlefinsOrganometallics, 24
C. Copéret, M. Chabanas, Romain Saint-Arroman, J. Basset (2003)
Homogeneous and heterogeneous catalysis: bridging the gap through surface organometallic chemistry.Angewandte Chemie, 42 2
Van BG, Ali, Alper (2000)
Chemo- and regioselective cyclohydrocarbonylation of alpha-keto alkynes catalyzed by a zwitterionic rhodium complex and triphenyl phosphiteThe Journal of organic chemistry, 65 13
L. Bonaga, M. Krafft (2004)
When the Pauson-Khand and Pauson-Khand type reactions go awry: a plethora of unexpected resultsTetrahedron, 60
A. Streitwieser, D. Reuben (1971)
Acidity of hydrocarbons. XXXV. Equilibrium acidities of phenylacetylene and tert-butylacetylene in cyclohexylamineJournal of the American Chemical Society, 93
B. Breit, R. Winde, K. Harms (1997)
PHOSPHABENZENE-RHODIUM CATALYSTS FOR THE EFFICIENT HYDROFORMYLATION OF TERMINAL AND INTERNAL OLEFINSJournal of The Chemical Society-perkin Transactions 1
F. Goettmann, C. Boissière, D. Grosso, F. Mercier, P. Floch, C. Sanchez (2005)
New hybrid bidentate ligands as precursors for smart catalysts.Chemistry, 11 24
I. Khand, G. Knox, P. Pauson, W. Watts (1971)
A cobalt induced cleavage reaction and a new series of arenecobalt carbonyl complexesJournal of The Chemical Society D: Chemical Communications
Frdric Goettmann, D. Grosso, Franois Mercier, F. Mathey, Clment Sanchez (2004)
New P^O ligand grafted on periodically organised mesoporous silicas for one-pot bifunctionnal catalysis: Coupling of base catalysed Knoevenagel condensation with in situ Rh catalysed hydrogenationElectronic supplementary information (ESI) available: NMR spectra, TEM micrographs, N2 adsorption/desorpChemical Communications
I. Nakamura, Yoshinori Yamamoto (2004)
Transition-metal-catalyzed reactions in heterocyclic synthesis.Chemical reviews, 104 5
S. Gibson, A. Stevenazzi (2003)
The Pauson-Khand reaction: the catalytic age is here!Angewandte Chemie, 42 16
Y. Ishii, K. Miyashita, K. Kamita, M. Hidai (1997)
Selective Hydroformylation of Internal Acetylenes by PdCl2(PCy3)2: Remarkable Synergistic Effect of Cobalt1Journal of the American Chemical Society, 119
B. Breit, W. Seiche (2001)
Recent Advances on Chemo-, Regio- and Stereoselective HydroformylationSynthesis, 2001
Jaime Blanco-Urgoiti, Loreto Añorbe, L. Pérez-Serrano, G. Domínguez, J. Pérez-Castells (2004)
The Pauson-Khand reaction, a powerful synthetic tool for the synthesis of complex molecules.Chemical Society reviews, 33 1
B. Breit, R. Winde, T. Mackewitz, R. Paciello, K. Harms (2001)
Phosphabenzenes as monodentate pi-acceptor ligands for rhodium-catalyzed hydroformylation.Chemistry, 7 14
Zirconia-silica mesoporous powders act as very efficient heterogeneous catalysts for both alkyne hydroformylation and Pauson-Khand reaction and yield regioselectivities opposite to those usually observed.
Chemical Communications – Pubmed
Published: Apr 3, 2007
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